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​Dear Jonathan,


The IPK is just a lump (cylinder) of platinum and Iridium that initially 17 nations agreed would be the international reference standard for the kg. By that definition there could be no uncertainty as there was no other international reference with which to compare it by measurement.


Similarly, with acceptance of the new definition the value of Plank's constant has no uncertainty as there is no other international reference to compare it with.  However it does now allow the uncertainty of the 'old' IPK to be estimated by measurement.


I hope this may help you get out more!


Best wishes,


Graham White


From: Clinical biochemistry discussion list <[log in to unmask]> on behalf of Jonathan Middle <[log in to unmask]>
Sent: Saturday, 17 November 2018 11:17 PM
To: [log in to unmask]
Subject: Re: SI
 
Thanks John!

This page at BIPM has some fascinating Q & As!  https://www.bipm.org/en/measurement-units/rev-si/faqs.html

I love this one, which concerns the uncertainty components:

image.png

Cheers

J



On Sat, Nov 17, 2018 at 9:49 AM John <[log in to unmask]> wrote:

Just in case list members may have not noticed this. The redefinition of the SI units is now upon us. On 16th November 2018, measurement scientists from more than 60 countries have come together to witness the vote on the redefinition of the International System of Units (SI), changing the world's definition of the kilogram, the ampere, the kelvin and the mole.

The biggest issue was that, the base unit kilogram is based on an artifact, a platinum-iridium cylinder (the international prototype kilogram, IPK) manufactured in 1879 and stored at the BIPM. There is an intrinsic uncertainty in the long-term stability of the IPK. In principle, this instability also impacts other SI units that depend on the kilogram, among which is the mole. The redefinition links the unit of mass to fundamental or atomic constants.

In practice, nothing will really change, but in an ISO dominated scientific world, where the provenance/traceability of every measurement matters, this is of some relevance.

Nice  Utube video explaining the makeover from the BIPM

 https://www.bipm.org/en/about-us/

Introduction to  the new definition of the mol that does not rely  on the mass of a kilogram found here from IUPAC

https://iupac.org/new-definition-mole-arrived/

The paper describing the new definition in some detail here

https://www.degruyter.com/view/j/pac.2018.90.issue-1/pac-2017-0106/pac-2017-0106.xml

FAQ’s from the BIPM here

https://www.bipm.org/utils/en/pdf/SI_FAQs_EN.pdf

As far as temperature is concerned   The  new  definition  of  the  kelvin  has  no  immediate  impact  on  the  status  of  the  widely-used  ITS-90  and  PLTS-2000  temperature  scales. So traceability back to reference thermometers should not be a problem, this is covered in the FAQ link above

Best wishes

John O’Connor

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------ACB discussion List Information-------- This is an open discussion list for the academic and clinical community working in clinical biochemistry. Please note, archived messages are public and can be viewed via the internet. Views expressed are those of the individual who posts and they are solely responsible for all message content. The ACB does not monitor posts. ACB Web Site http://www.acb.org.uk Green Laboratories Work http://www.laboratorymedicine.nhs.uk List Archives http://www.jiscmail.ac.uk/lists/ACB-CLIN-CHEM-GEN.html List Instructions (How to leave etc.) http://www.jiscmail.ac.uk/
------ACB discussion List Information-------- This is an open discussion list for the academic and clinical community working in clinical biochemistry. Please note, archived messages are public and can be viewed via the internet. Views expressed are those of the individual who posts and they are solely responsible for all message content. The ACB does not monitor posts. ACB Web Site http://www.acb.org.uk Green Laboratories Work http://www.laboratorymedicine.nhs.uk List Archives http://www.jiscmail.ac.uk/lists/ACB-CLIN-CHEM-GEN.html List Instructions (How to leave etc.) http://www.jiscmail.ac.uk/