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Great discussion!

Regarding the reversibility of melting reactions, in a closed system (i.e. no melt loss) the muscovite dehydration melting reaction should be 100% reversible. Similarly, in a closed system the melting of biotite (biotite + sillimanite or kyanite = melt + garnet) should be 100% reversible. There are many examples of “late” muscovite and garnet resorbed by biotite and/or Al2SiO5 in migmatites to attest to this. Fall Mountain, New Hampshire is an excellent example!

Cheers,

Frank



Frank Spear
Professor and Department Head
Department of Earth and Environmental Sciences
Rensselaer Polytechnic Institute
110 8th St., Troy NY 12180
518-276-6103
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On Jun 24, 2018, at 1:59 PM, Bruce Yardley <[log in to unmask]> wrote:

Lots of excellent points that are not in dispute from Yong-Fei and John, but I still have problems with some of the details.
 
Yong-Fei seems to be saying that dehydration melting reactions are not reversible, so that water always accumulates in the melt beyond what enters minerals as they crystallise, and is therefore available to exsolve at the wet solidus.
 
John has a water phase exsolving from melt above the wet solidus. I’m sure you can do that in an experiment, but surely not in a rock-dominated natural system where the amount of water will be very limited? Or, since the phase rule has something to say when extra phases appear, is it a feature of systems with a relatively large number of degrees of freedom?
 
Bruce
 
Bruce Yardley
Emeritus Professor
School of Earth & Environment
University of Leeds
Leeds LS2 9JT
UK
 
Tel +44 (0)7745 132560
 
 
From: Clemens, JD, Prof [[log in to unmask]] [mailto:[log in to unmask]] 
Sent: 24 June 2018 17:35
To: Metamorphic Studies Group <[log in to unmask]>; Bruce Yardley <[log in to unmask]>
Subject: Re: [geo-metamorphism] Crustal anatexis
 
I think that, for melts formed by fluid-absent reactions, H2O will only be released at the wet solidus if the melt remains at its pressure of formation. If it ascends and crystallises, fluid will exsolve at some T above the wet solidus, at the point where crystallisation pushes melt H2O content to the saturation level for that P. The solidus will only be reached with further T drop and further crystallisation.
 
Please also remember that a wet melt will not freeze immediately on ascent unless it remains in contact with the restitic and peritectic minerals in its source. If the melt is segregated from the solids then it is far more mobile, since it’s solidus is at T well below the solidus of the source rock.
 
All this junk was looked into in:
Clemens and Droop (1998) Lithos 44: 21-36.
 

I hope I remembered it correctly!

Prof. J. D. Clemens  
Department of Earth Sciences
University of Stellenbosch
Private Bag X11
Matieland 7602
South Africa 
Phone: +27 21 808 3159
Cell: +27 78 747 4864
 
----------------------------------------
Our passions cannot alter the facts, only hide them from us.
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On 24 Jun 2018, at 13:38, Bruce Yardley <[log in to unmask]> wrote:

Hi Yong-Fei
 
Not sure I understand the last part of your statement: “water is released from these crustal rocks through the breakdown of hydrous minerals and the exsolution of structural hydroxyl and molecular water from nominally anhydrous minerals. While this leads to dehydration melting of the crustal rocks on the one hand, it also results in hydration of adjacent rocks for partial melting at temperatures on and above the wet solidus of these rocks on the other hand.
It sounds as though you are suggesting that a melt produced by deydration melting releases water as it crystallises  even while at a temperature above the wet solidus? If everything is happening at constant pressure and close to equilibrium, surely the water from the melt is just going to be incorporated into the hydrous minerals as they regrow on cooling? And if pressure has changed, for example so that a melt generated by muscovite breakdown now crystallises sillimanite + K-feldspar, the water still remains dissolved in the melt until it has crystallised to the point of water-saturation, i.e. the wet solidus. (In an experiment you can have excess water, melt the rock fully and still keep heating the resulting water-saturated melt above the wet solidus, but the real world does not work like that). If water released from anatectic melt as it crystallises on the wet solidus is going to flux water saturated melting of the adjacent rocks you have to have the special case of country rocks with a lower melting point, otherwise you contravene the second law of thermodynamics!
 
I think it is more likely in the muscovite melting example  that the water released when the anatectic melt solidifies (assuming it hasn’t moved far) will be used up driving sub-solidus alteration of sillimanite + K-felspar to coarse, high-T muscovite (rather than typical low-T retrograde shimmer aggregate).
 
Bruce
 
Bruce Yardley
Emeritus Professor
School of Earth & Environment
University of Leeds
Leeds LS2 9JT
UK
 
Tel +44 (0)7745 132560
 
 
From: Metamorphic Studies Group [mailto:[log in to unmask]] On Behalf Of Yong-Fei?Zheng
Sent: 23 June 2018 00:04
To: [log in to unmask]
Subject: Re: [geo-metamorphism] Crustal anatexis
 
Dear John,
 
The physicochemical mechanisms for partial melting of crustal rocks include heating, decompression and adding water (hydration). There is no free water in crustal rocks when they were buried to middle to lower crust depths. Water in the crustal rocks of crystalline basement is present in the forms of structural hydroxyl and molecular water in both hydrous and nominally anhydrous minerals. By either heating or decompression, water is released from these crustal rocks through the breakdown of hydrous minerals and the exsolution of structural hydroxyl and molecular water from nominally anhydrous minerals. While this leads to dehydration melting of the crustal rocks on the one hand, it also results in hydration of adjacent rocks for partial melting at temperatures on and above the wet solidus of these rocks on the other hand.
 
In experimental petrology, the dehydration melting was designed to occur in the absence of aqueous solutions (water-absent melting), whereas the hydration melting was designed to proceed in the presence of aqueous solutions (water-present melting). In either case, water is preferentially partitioned into melts as soon as crustal anataxis takes place, leaving relatively anhydrous residues as granulites. As a consequence, granites crystallized from felsic melts are much more enriched in water than granulites. While granitic melts can be produced by either dehydration melting or hydration melting, the removal of water from granulites always proceeds through the dehydration melting.
 
Migmatites can be produced through either dehydration melting or hydration melting. The key is almost no physical separation of partial melts from parental rocks. Partial melting for migmatitization may occur in three phases: (1) decompressional exhumation of the deeply subducted crustal rocks from subarc to forearc depths in the late stage of collisional orogeny; (2) thinning of the collision-thickened crust during foundering of orogenic roots; (3) heating of the thinned crust in the postcollisional stage. In either case, leucosome is enriched in water than mesosome unless hydrous minerals are concentrated in the mesosome.
 
Best,
Yong-Fei





-----原始邮件-----
发件人:"Clemens, JD, Prof [[log in to unmask]]" <[log in to unmask]>
发送时间:2018-06-22 17:34:00 (星期五)
收件人: [log in to unmask]
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: Re: Crustal anatexis

Migmatites tend to be fluid-present melting phenomena. 
Granites tend to be fluid-absent melting phenomena.
 
In wet melting, as the sniff of H2O runs out, melting grinds to a halt, unless T keeps going up and you then reach the high-T mica and amphibole melting reactions.
 
Prof. John D. Clemens
Dept of Earth Sciences
University of Stellenbosch
+27 (0)21 808 3159



On 22 Jun 2018, at 11:21, Tom.Argles <[log in to unmask]> wrote:
 
I have ‘occasionally’ found both large-scale leucogranites and abundant migmatites along the entire arc of the collisional Himalayan orogeny, which would seem to suggest considerable crustal anatexis. Other orogens show similar features. There seems to be plenty of heat there…
 
What I find more interesting is the question of why the partial melt (sorry, magma) migrates out of some rocks but becomes ‘frozen’ in place in others. Extension may help but surely melt fraction has a role to play? Little bits of melt may get stuck; more melt will get connected and find a way to escape?
 
So maybe orogenic migmatites reflect generally smaller melt volumes and hence less chance of escape (and more chance of preservation!)? We see more of the process and less of the product…
 
Tom
 
From: Metamorphic Studies Group [mailto:[log in to unmask]] On Behalf Of Yong-Fei?Zheng
Sent: 22 June 2018 10:01
To: [log in to unmask]

Subject: Re: [geo-metamorphism] Crustal anatexis
 

Dear Martin,

Compressional settings for crustal thickening are characterized by low geothermal gradients and thus by Alpine-type HP to UHP metamorphism at blueschist to eclogite facies, so that no crustal anatexis can take place in the stage of crustal thickening during collisional orogeny. In contrast, extensional settings are produced by lithospheric thinning, resulting in shallowing of the lithosphere/asthenosphere boundary and thus upwelling of the asthenospheric mantle. This is able to transfer the high heat flow from the underlying asthenospheric mantle into the overlying thinned lithospheric mantle, making Buchan-type HT to UHT metamorphism at amphibolite to granulite facies. Both metamorphic dehydration and partial melting of crustal rocks are caused by asthenospheric heating of the thinned lithosphere, resulting in crustal anatexis in such extensional settings.As a consequence, the crustal anatexis is prominent subsequent to the lithospheric thinning and thus responsible for reworking of preexising collisional orogens in backarc and continental rifts (rifting orogeny).

Best,

Yong-Fei

-----原始邮件-----
发件人:"Martin Hand" <[log in to unmask]>
发送时间:2018-06-22 16:32:12 (星期五)
收件人: [log in to unmask]
抄送: 
: Re: Crustal anatexis

Agreed, heat and/or volatiles.  But why extensional settings would facilitate magma transfer more than other settings seems more paradigm, than actualistic.
 
Martin Hand
Department of Earth Sciences
University of Adelaide
Phone : +61 (0)8 831 36794
Phone : +61 (0)8 831 35324
Mobile: +61 (0)419 314 306
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IMPORTANT: This message may contain confidential or legally privileged information. If you think it was sent to you by mistake, please delete all copies and advise the sender. For the purposes of the SPAM Act 2003, this email is authorised by The University 
 
 
From: Metamorphic Studies Group <[log in to unmask]> On Behalf Of Clemens, JD, Prof [[log in to unmask]]
Sent: Friday, 22 June 2018 5:24 PM
To: [log in to unmask]
Subject: Re: [geo-metamorphism] Crustal anatexis
 
All you need is heat, if you want granulite-facies partial melting.
The extensional settings may help with getting mantle heat into the crust and with getting partial melt (or, more correctly, magma) out of the anatectic zone.

 

Prof. John D. Clemens
Dept of Earth Sciences
University of Stellenbosch
+27 (0)21 808 3159

 

On 22 Jun 2018, at 09:49, Martin Hand <[log in to unmask]> wrote:
 
Dear all,
 
Does crustal anatexis mainly occur in extensional settings?  In the current Earth, large-scale anatexis appears to be occurring in the Tibetan crust, and also at the base of magmatic arcs.  
 
 
Martin Hand
Department of Earth Sciences
University of Adelaide
Phone : +61 (0)8 831 36794
Phone : +61 (0)8 831 35324
Mobile: +61 (0)419 314 306
CRICOS Provider Number 00123M
-----------------------------------------------------------
IMPORTANT: This message may contain confidential or legally privileged information. If you think it was sent to you by mistake, please delete all copies and advise the sender. For the purposes of the SPAM Act 2003, this email is authorised by The University 
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From: Metamorphic Studies Group <[log in to unmask]> On Behalf Of Yong-Fei?Zheng
Sent: Friday, 22 June 2018 5:07 PM
To: [log in to unmask]
Subject: Re: [geo-metamorphism] Crustal anatexis
 
Dear Mallickarjun,
 
At supersolidus temperatures, crustal rocks undergo partial melting to produce a sizable volume of anatectic melts. This process is common during high-grade metamorphism at amphibolite- to granulite-facies conditions. Migmatites are its typical products in which anatectic melts were not escaped from the anatectic systems.
 
Such a kind of crustal anatexis mainly occurs in extensional settings such as backarc and continental rifts, where the lithosphere is significantly thinned to cause upwelling of the asthenospheric mantle, transferring high heat flow into the lower crust for metamorphic dehydration and partial melting at crustal depths. While dehydrated and melt-extracted residues show HT to UHT granulitization, releassed fluids (aqueous solutions) result in amphibolitization of the overlying crustal rocks and escaped melts (hydrous, felsic) give rise to granitic intrusives in different sizes. 
 
Yong-Fei
--
***********************************************************************
Dr. Yong-Fei Zheng
Professor of Geochemistry
School of Earth and Space Sciences
University of Science and Technology of China
Hefei 230026, China
Tel & Fax: +86 551 63603554

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-----原始邮件-----
发件人:"Mallickarjun Joshi" <[log in to unmask]>
发送时间:2018-06-21 22:06:08 (星期四)
收件人: [log in to unmask]
抄送: 
:

Dear All,
 
I wonder under what conditions a sizable volume of  the  anatectic melt formed as a consequence of high grade metamorphism in pelites would not be able to escape the system? 
 
Admittedly, metamorphism outlasting the deformation should be a likely precondition.
 
Moreover, should it also shed some light on the tectonic set up other than that  it is likely to have formed during the penultimate stages of the orogeny.
 
I would much appreciate  your opinion and any suggestions for references to understand the problem.
 
Thanks and regards

Mallickarjun Joshi
Centre of Advanced Study in Geology
Banaras Hindu University
India
 

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Professor of Geochemistry

School of Earth and Space Sciences

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Hefei 230026, China

Tel & Fax: +86 551 63603554

Email: [log in to unmask]

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Professor of Geochemistry

School of Earth and Space Sciences

University of Science and Technology of China

Hefei 230026, China

Tel & Fax: +86 551 63603554

Email: [log in to unmask]

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