Can't resist folks - lovely demo of metamorphic kinetics.
Ralf Dohmen and I did a paper in 2003 (Am Min) where we showed
that a controlling factor in such reactions is the efficiency of
transport in grain boundaries - efficiency being the product of
solubility (i.e. concentration) of a species in the grain boundary
region x rate of transport ( meaured, for example, by diffusion
coefficient). The latter is responsible for time dependence.
Increasing either quantity, or decreasing either one, has the same
effect.
Kurt's sample has all the time in the world (I assume), but a
solubility / concentration problem; Bernardo's sample has no
problems with transport (melt present) / concentration, but a time
problem (rapidly quenched xenoliths)....pretty similar results.
Effect is a little like momentum in physics I tell my students
(if they care to listen) - increase mass or increase
velocity.....same net effect.
[log in to unmask]" type="cite">Wonderfull microphotographs in this topic !
Bernardo
I guess that your sample is a xenolith
C.........
Prof. Christian NICOLLET
Laboratoire Magmas et Volcans
Campus Universitaire des Cézeaux
6 Avenue Blaise Pascal
http://christian.nicollet.free.fr/
63178 AUBIERE Cedex
Le 09/12/2016 à 16:15, Bernardo Cesare a écrit :
[log in to unmask]" type="cite">Dear all,Enclosed an example from El Hoyazo, Spain, similar to the one reported by Kurt, with the control of the neighbouring phase on reaction development, but also WITH melt (glass visible in the upper part of the BSEM image). Ilmenite forms with Opx and melt because biotite has 6 wt% TiO2.Sorry, Martin…
Cheers,bernardo
Dear all,
This is an interesting topic and thank you all for the inspiring discussion. I add a photomicrograph (250 kb) to this discussion which could be interesting to you. It shows an Opx crust growing from biotite and replacing the mica by the prograde reaction Bt + Qtz => Opx + Kfs + H2O. Interestingly, the Opx crust only develops where Bt is (was) in direct grain contact to Qtz, no Opx grows along Kfs + Bt and Crd + Bt contacts. Biotite is the only hydrate mineral in this granulite, other minerals include Crd, Grt, Sap, and Sil. The texture can be interpreted in different ways. My favorite is: The small amount of H2O released by the dehydration of the mica does not saturate the grain boundaries with a fluid phase. Chemical communication distance along the grain boundaries is small with the consequence that SiO2 from Qtz does not make it to Bt + Kfs boundaries. The local texture and also the texture of the rock does not suggest the presence of a melt. So, the picture has it all what Martin Hand wanted to see.
Kurt Bucher
For more details see: Droop & Bucher-Nurminen 1984: Jour. Petrol., 25, 766-803.
*From:*Metamorphic Studies Group [mailto:[log in to unmask]] *On Behalf Of *Martin Hand
*Sent:* Wednesday, December 07, 2016 1:03 PM
*To:* [log in to unmask]
*Subject:* [geo-metamorphism] Subsolidus prograde opx in metapelite
Dear all,
Has anyone come across or know of examples where opx has grown during prograde metamorphism of metapelite at subsolidus conditions?
Martin Hand
Department of Earth Sciences
University of Adelaide
Phone : +61 (0)8 831 35324
http://www.adelaide.edu.au/geothermal/
http://www.adelaide.edu.au/directory/martin.hand
--
Kurt Bucher (Prof. Dr.)
Institute of Mineralogy and Geochemistry
University of Freiburg
Albertstrasse 23b D-79104 Freiburg Germany
Phone 49-761-203-6417 (direct) 6396 (general office) 6407 (FAX)
http://www.minpetro.uni-freiburg.de
[log in to unmask]
<Fig.7.14 Bt breakdown.jpg>
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