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In terms of waste classification, you only turn to the pH test >11.5 for wastes that contain complex mixtures that you can't clearly define in terms of their composition. In this case you can't assess for the applicable risk phrases and must turn to pH,   remembering to consider the acid / alkali reserve. If this does not produce a clear answer you are left with very few test alternatives.
 
Additionally, if the material is generating a pH>11.5 at it's own pH during a WAC test it should not be sent to landfill without pre-treatment.  This is because the waste shows corrosive properties and corrosive wastes are prohibited from landfill. This is different to the waste being classified as H8 Corrosive.  
 
In your case it sounds to me that the latter case may apply, although this would depend upon the complexity of the waste and the analysis undertaken.
 
hope this helps
 
Ben Rees MSc CGeol
Environmental Geoscientist

Geotechnology
Ty Coed
Cefn-yr-Allt
Aberdulais
Neath
SA10 8HE

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From: Contaminated Land Management Discussion List on behalf of Adam Czarnecki
Sent: Fri 7/25/2008 13:45
To: [log in to unmask]
Subject: pH & Waste Classification

Can a soil be deemed to be Hazardous Waste if the pH is >11.5?

 

The analysis of other “”dangerous substances” suggests an absence of risk phrases R1 to R68.

 

Any help would be appreciated.

 

Adam

 

 

 

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Adam Czarnecki

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