Hi Nick,
Why not have them read Kropotkin in his own words?
'What Geography Ought To Be' - http://dwardmac.pitzer.edu/Anarchist_Archives/kropotkin/whatgeobe.html
'Anarchism' - http://dwardmac.pitzer.edu/Anarchist_Archives/kropotkin/britanniaanarchy.html
Otherwise Jim MacLaughlin's new book "Kropotkin and the Anarchist Intellectual Tradition" is a fantastic brief overview, while Iain McKay's "Direct Struggle Against Capital: A Peter Kropotkin Anthology" is an amazing and massive collection of various writings.
Cheers,
Simon
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